2.2 CMP-induced defects beyond dishing
Cu dishing rarely occurs as an isolated phenomenon. In practical CMP conditions, oxide
roll-off and fang formation are frequently generated concurrently and play a decisive
role in determining post-CMP surface integrity and subsequent hybrid bonding reliability.
Therefore, for a bonding-centric understanding of CMP, these defects are discussed
together with dishing rather than treated as secondary effects. Oxide roll-off refers
to the localized recession of the dielectric near the Cu–dielectric boundary, as already
shown in Figure 1. This phenomenon originates from the local pressure amplification and removal rate
selectivity at Cu edges during CMP. Park et al. demonstrated that the intrinsic hardness
of Cu films (~2.0 GPa) transitions into composite hardness influenced by the substrate
when the polishing depth exceeds 20% of the film thickness. This suggests that the
shifting mechanical response of the film-substrate system can further fluctuate the
MRR and aggravate dishing during the final stages of CMP[12]. According to Preston’s equation (Eq. 2), the material removal rate R(x,t) in CMP, which varies with time and position, is
proportional to the local pressure and wear coefficient and can be written as[10]:
where k(x) is the wear coefficient dependent on the material and slurry chemical composition,
v(x) is the relative velocity, and p(x,t) is the local pressure distribution.
When Cu dishing develops, even at the nanometer scale, a height gradient forms between
the recessed Cu pad and the surrounding dielectric. According to the pressure–gap
relationship described in Eq. 3, this topographical non-uniformity locally increases the polishing pressure at the
Cu–dielectric boundary, accelerating dielectric erosion.
Integrating the Preston equation (Eq. 3) with time yields the change in surface topography T(x,t).
Here, T and w is the time-dependent function of the deformed pad surface topography,
and a reduction in local gap (d = w - T) leads to an increase in the local polishing
pressure.
As a result, oxide roll-off progresses simultaneously with Cu dishing, effectively
increasing the local recess depth beyond what is captured by average dishing measurements.
This behavior is particularly pronounced in fine-pitch patterns, where boundary effects
dominate, as previously reported for narrow Cu pad spacing and small pad sizes[4,11], as shown in Figure 4.
Fig. 4. (a) Cu dishing depth with various Cu pad spaces depends on Cu pad size and
(b) dishing size after 150 s of overpolishing depends on Cu pad size[4,11].
Fang formation is another CMP-induced defect closely linked to dishing and slurry
chemistry. During CMP, non-uniform formation and removal of Cu oxide or passivation
layers can lead to partial retention or redeposition of Cu reaction products near
the Cu–dielectric interface. With increasing over-polishing time, these residual features
can evolve into protruding ridge-like structures, commonly referred to as fangs. From
a topographical standpoint, fang formation appears to locally counteract Cu dishing;
however, it is highly detrimental to hybrid bonding. Fang-induced protrusions generate
severe local stress concentrations during pre-bonding contact and post-annealing,
increasing the likelihood of dielectric cracking and interfacial delamination. This
behavior is consistent with reported numerical analyses showing strong stress amplification
at non-uniform Cu/dielectric interfaces during thermal cycling[6].
The combined presence of dishing, oxide roll-off, and fang formation fundamentally
alters the post-CMP surface relevant to hybrid bonding. Even when the average Cu dishing
depth is controlled below 5 nm, excessive oxide roll-off can locally increase the
effective Cu recess beyond the diffusion capability of Cu atoms during low-temperature
annealing, leading to persistent interfacial voids[5,6]. Conversely, fang formation can cause premature localized Cu–Cu contact, resulting
in non-uniform bonding pressure distribution and incomplete bonding in adjacent regions.
This explains why CMP processes optimized solely for Cu removal rate or global dishing
control often fail to achieve high bonding yield, particularly under low-temperature
(<250 °C) hybrid bonding conditions.
From the perspective of hybrid bonding, CMP must therefore be regarded as a bonding-critical
surface engineering step, not merely a planarization or Cu removal process. The CMP
process preceding hybrid bonding must simultaneously suppress Cu dishing, minimize
oxide roll-off, and eliminate fang formation while maintaining ultra-low surface roughness
and chemical cleanliness. Achieving this requires holistic optimization of slurry
chemistry (oxidizer concentration, corrosion inhibitors, and abrasive selectivity),
polishing pad compliance, and multi-step CMP strategies capable of correcting edge-related
defects. As demonstrated in recent studies on slurry design and multi-step CMP correction
schemes, controlling removal rate between Cu and dielectric is essential not only
for dishing mitigation but also for suppressing secondary defects that directly impact
bonding reliability[11,32,35].
In summary, a CMP process that simply removes Cu is insufficient for hybrid bonding
applications. Instead, the CMP process completed immediately before bonding must be
optimized with consideration of dishing, oxide roll-off, and fang formation, as these
defects collectively determine interfacial contact uniformity, Cu diffusion efficiency,
and long-term bonding reliability in advanced 3D heterogeneous integration.
The geometric structure of the Cu pad pattern is also a factor determining the magnitude
of dishing. According to a study by Ji et al., as shown in Figure 4, expanding the inter-pad spacing from 2 µm to 4 µm increases the dishing depth for
the same pad size. Notably, 2 µm pads react more sensitively to spacing changes than
4 µm pads[4]. When Cu pad spacing was 2 µm and 3 µm, a large dishing depth difference of approximately
8 nm was observed between 2 µm and 4 µm pads, but this difference decreased to a negligible
0.75 nm when the spacing was 4 µm.
Therefore, according to Eq. 3, as the over-polishing time increases, the cumulative material removal at the bottom
of the Cu patterns increases, thereby exacerbating the dishing phenomenon[10]. In particular, dishing deviation was noted as a major variable heavily dependent
on the initial electroplated Cu size and the increase in over-polishing time. Liu
et al. confirmed that after 150 seconds of over-polishing, 50 µm pads had a dishing
depth of 476 nm, while 10 µm pads had 159 nm, indicating that larger pads have a higher
rate of dishing increase over time, resulting in a larger average dishing depth[11]. This result shows significantly larger dishing compared to the 275 nm dishing depth
of the 44.3 µm diameter Cu-filled TSV reported by Roh et al.[9]. This is because Roh et al.'s result involved a W-Cu alloy. Since the hardness of
the alloy is higher than that of pure Cu (as reported by Liu et al.[11]), the dishing depth is expected to be smaller.
The removal rate selectivity that is determined by the slurry composition is another
factor influencing dishing. Seo et al. mentioned that raising the oxidizer (H2O2) concentration enhances the formation of a protective film on the Cu surface, showing
a tendency to reduce dishing[3]. Nguyen et al. presented results saying that for 100 µm wide Cu lines, the dishing
depth was approximately 250 nm at an oxidizer concentration of 7.5% but decreased
to about 120 nm at a concentration of 15%[13].
To control excessive chemical etching and minimize Cu dishing in CMP, adjustment of
corrosion inhibitors in the slurry is necessary. In a paper by Zhao et al. regarding
CMP using Ru, the concentration of the corrosion inhibitor 5-methylthio-1H-tetrazole
(MTT) was adjusted to the 2000 ppm level to optimize the Cu/Ru removal rate selectivity
to 1:1.18[14]. This reduced the average dishing depth in the 100 µm/100 µm region from 960 Å (96
nm) to 490 Å (49 nm), and in the 50 µm/50 µm region from 650 Å (65 nm) to 410 Å (41
nm).
Additionally, Ming et al. reported a reduction in dishing and scratching by changing
and controlling the slurry when applying Damascene CMP to the fabrication of IGZO
(InGaZnO) transistors used in DRAM technology[15]. The conventional oxide slurry A, with a high solid content of 15.9%, caused high
levels of scratching after CMP and had a high IZO/SiN removal rate selectivity of
10:1, causing IZO dishing. Slurry B, proposed as an alternative, featured a low solid
content (0.6%), acidity (pH ~ 2), H2O2 oxidizer, and 100 ppm Fe catalyst. It significantly reduced the IZO/SiN removal rate
selectivity to 3:1, thereby reducing the dishing value to 16 nm in 100 nm / 100 nm
hole patterns. As seen in the effects of the strategies mentioned in Figure 5, the difference in removal rates significantly affects dishing.
Fig. 5. Cu dishing depth reduction by various methods[13-15].
The uniformity of dishing after the CMP process is influenced by the micro-topography
from preceding processes as well. Cho et al. suggested that sidewall scallops generated
during DRIE (deep reactive ion etching) for TSV of Figure 6 are a major factor inhibiting the continuity of the Cu seed layer in the subsequent
deposition process[16]. This causes non-uniform Cu filling, leading to reduced uniformity in the CMP process.
In addition, if internal voids generated during the Cu filling process exist near
the surface, the pressure applied during CMP can cause local collapse of those areas,
inducing severe dishing.
Fig. 6. Scallop formation during Bosch DRIE process. Reproduced from Ref. 13 with
permission from MDPI.
Vlassak et al.[10] reported that according to Eq. 4, a reduction in the local gap (d = w - T) increases the local pressure p at the pad-wafer
interface, where T(t) and w(t) denote the wafer and deformed pad surface topographies,
respectively. This locally increases the material removal rate during CMP, intensifying
dishing in certain areas.
Although TSV-based structures have yielded several fundamental insights into Cu dishing,
removal rate selectivity, and pattern density effects (Figures 3, 4, and 6), hybrid Cu bonding places fundamentally distinct and substantially more rigorous
demands on post-CMP surface integrity.