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Korean Journal of Metals and Materials > Epub ahead of print
김한솔1 · 구혜원1 · 송민주1 · 정중희1 · 오용준1 · 송창은2 · 홍기하1,*
A-site 조성 제어를 통한 FA기반 페로브스카이트의 상안정화 및 전단 코팅 최적화 연구
Received: 14 January 2021;  Accepted: 4 March 2021.  Published online: 6 April 2021.
ABSTRACT
Halide perovskite solar cells have been attracting tremendous attention as next-generation solar cell materials because of their excellent optical and electrical properties. Formamidinium lead tri-iodide (FAPbI3) exhibits the narrowest band gap among lead iodide perovskites and shows excellent thermal and chemical stability, also. However, the large-area coating of FAPbI3 needed for commercialization has not been successful because of the instability of the black phase of FAPbI3 at ambient temperature. This study presents a compositional engineering direction to control the polymorph of the FAPbI3 thin film for the shear coating processes, without halide mixing. By adopting a hot substrate above 100 oC, our shear coating process can produce the black phase FA-based halide perovskites without halide mixing. We carefully investigate the Cs- FA and MA-FA mixed lead iodide perovskites’ phase stability by combining the study with thin-film fabrication and ab initio calculations. Cs-FA mixing shows promising behaviors for stabilizing α-FAPbI3 (black phase) compared with MA-FA. Stable FA-rich perovskite films cannot be achieved via shear coating processes with MA-FA mixing. Ab initio calculations revealed that Cs-FA mixing is excellent for inhibiting phase decomposition and water incorporation. This study is the first report that FA-based halide perovskite thin films can be made with the shear coating process without MA-Br mixing. We reveal the origin of the stable film formation with Cs-FA mixing, and present future research directions for fabricating FA-based perovskite thin films using shear coating.
Keywords: perovskite, shear-coating, solar-cell, large-area, FAPbI3
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