| Home | E-Submission/Review | Sitemap | Editorial Office |  
Korean Journal of Metals and Materials > Epub ahead of print
이혜령 · 김광배 · 송오성
TiO2의 GO 혼합 양에 따른 페로브스카이트 태양전지의 물성 연구
Received: 22 April 2019;  Accepted: 2 June 2019.  Published online: 5 June 2019.
The photovoltaic properties of perovskite solar cells (PSCs) were investigated by adding graphene oxide (GO) to the electron transport layer of TiO2. The PSCs were fabricated with a glass/FTO/BL-TiO2/meso-TiO2 + GO/perovskite/HTL/Au electrode structure by adding various contents of GO (0.0, 0.3, 0.5 and 0.7 wt%) to the TiO2 layer. To analyze the photovoltaic characteristics and transmittance of the TiO2 layer of the PSCs according to the GO content, solar simulator and ultraviolet-visible-near-infrared spectroscopy were used, respectively. Atomic force microscopy and field emission scanning electron microscope were used to analyze the microstructures of both the TiO2 layer and the perovskite layer. The results of the photovoltaic characteristics indicated that energy conversion efficiency (ECE) was gradually increased to 12.70%, 13.13%, 14.19%, and 12.63% for 0.0, 0.3, 0.5, and 0.7 wt% GO contents, respectively. The highest ECE was observed at a GO content of 0.5 wt%, and a decrease in the ECE was confirmed at higher levels. The increase in ECE was confirmed by measuring short circuit current density (Jsc) and shunt resistance (Rsh) which increased with the GO addition. However, when an excessive amount of GO content was added, a decrease in the ECE was observed, due to the decrease in Jsc by the reduction in transmittance. In particular, an increase in the perovskite crystal size caused an increase in the ECE, due to the increased rms of TiO2 at 0.5 wt% GO. With the 0.7 wt% GO TiO2 layer, the perovskite grain size was decreased by the reduction in rms, and this resulted in a decrease in Jsc and ECE. These results suggest that we might improve the efficiency of perovskite solar cells by adding the proper amount of GO to the TiO2 layer.
Keywords: electoron transport layer, graphene oxide, perovskite grain, AFM, perovskite solar cells
PDF Links  PDF Links
Full text via DOI  Full text via DOI
Download Citation  Download Citation
Related article
Editorial Office
The Korean Institute of Metals and Materials
6th Fl., Seocho-daero 56-gil 38, Seocho-gu, Seoul 06633, Korea
TEL: +82-70-4266-1646   FAX: +82-2-557-1080   E-mail: metal@kim.or.kr
About |  Browse Articles |  Current Issue |  For Authors and Reviewers
Copyright © The Korean Institute of Metals and Materials. All rights reserved.                 Developed in M2Community