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Effect of HCl Concentration on the Oxidation of LIX 63 and the Subsequent Separation of Pd(II), Pt(IV), Ir(IV) and Rh(III) by Solvent Extraction
Thi Hong Nguyen, Man Seung Lee
Korean J. Met. Mater. 2016;54(10):768-774.   Published online 2016 Oct 5
DOI: https://doi.org/10.3365/KJMM.2016.54.10.768

Abstract
During the selective extraction of Pd(II) by LIX 63 from 6 M HCl solutions containing platinum group metals, an oxidation-reduction reaction occurs between the LIX 63 and Ir(IV). Since the reduced Ir(III) cannot be extracted by solvating and amine extractants, the oxidation-reduction reaction has a significant effect on the separation..... More

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