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Extraction Behavior of Hydrogen Ion by an Ionic Liquid Mixture of Aliquat 336 and Cyanex 272 in Chloride Solution
Minh Nhan Le, Seong Ho Son, Man Seung Lee
Korean J. Met. Mater. 2019;57(3):162-169.   Published online 2019 Feb 8
DOI: https://doi.org/10.3365/KJMM.2019.57.3.162

During the extraction of metal ions from a weak acidic chloride solution by ionic liquids consisting of an organophosphorus extractant and Aliquat 336, the equilibrium pH is sometimes observed to be higher than the initial pH. To compare the hydrogen ion extraction behavior of tertiary and quaternary amines, Alamine 336,..... More

Solvent Extraction of Tb(III) from Hydrochloric Acid Solution with Cyanex 272, Its Mixture and Ionic Liquid
염산용액에서 Cyanex 272 및 혼합용매와 이온성 액체에 의한 Tb(III)의 용매추출
Chang Geun Oh, Man Seung Lee
오창근, 이만승
Korean J. Met. Mater. 2018;56(12):870-877.   Published online 2018 Dec 5
DOI: https://doi.org/10.3365/KJMM.2018.56.12.870

Cyanex 272 shows the highest separation factor for the rare earth elements from hydrochloric acid solution among the organophosporus acidic extractants, D2EHPA and PC 88A. Solvent extraction of Tb(III) from weak hydrochloric acid solution with an initial pH 3 to 6 was compared with Cyanex 272, its mixture with Alamine..... More

                           Cited By 1
Diluents Role in Extraction and Possible Separation of Light Rare Earth Elements from Chloride Solutions by using Cyanex<sup></sup> 272 used as an Extractant
Rajesh Kumar Jyothi, Hae-Rim Kim, Joon Soo Kim, Kyeong-Woo Chung, Jin-Young Lee
Korean J. Met. Mater. 2018;56(10):763-771.   Published online 2018 Oct 5
DOI: https://doi.org/10.3365/KJMM.2018.56.10.763

The present paper deals with liquid-liquid extraction studies and the possible separation of light rare earths (LREs) from chloride solutions. Aromatic diluents such as benzene, toluene and xylene were tested for LREs extraction and possible separation from chloride solutions. Bis(2,4,4-triethylpentyl)phosphinic acid (trade name Cyanex® 272) was used as an extractant..... More

Comparison of Counter Current Extraction Process of Pr & Nd Separation using Cyanex 572 and PC88A
Cyanex 572와 PC88A를 사용하여 Pr 및 Nd 분리 시 향류추출 공정 비교
Joo-eun Lee, Hong-Il So, Yeon-Chul Cho, Jae-Woo Ahn, Hong-in Kim, Jin-young Lee
이주은, 소홍일, 조연철, 안재우, 김홍인, 이진영
Korean J. Met. Mater. 2018;56(8):597-604.   Published online 2018 Aug 5
DOI: https://doi.org/10.3365/KJMM.2018.56.8.597

This study designed a counter current extraction process for comparing the separation efficiencies that are obtained using Cyanex 572 and PC88A for the elements in a Pr and Nd mixed solution. This process involves multiple extraction and scrubbing processes using a mixer settler. The process parameters are calculated using an..... More

Comparison of the Extraction and Separation Behavior of La, Ce, Pr, Nd, Sm from Light Rare Earth Mixed Solutions by PC88A and Cyanex 572
경희토류 혼합용액에서 PC88A와 Cyanex 572에 의한 La, Ce, Pr, Nd, Sm의 추출·분리 거동 비교
Yeon-Chul Cho, Joo-eun Lee, Hong-Il So, Jae-Woo Ahn, Hong-in Kim, Jin-young Lee
조연철, 이주은, 소홍일, 안재우, 김홍인, 이진영
Korean J. Met. Mater. 2018;56(2):146-154.   Published online 2018 Feb 5
DOI: https://doi.org/10.3365/KJMM.2018.56.2.146

Solvent extraction of La, Ce, Pr, Nd and Sm from chloride solutions was studied using PC88A and Cyanex 572 as the extractants. Our results indicated that the acidity of the aqueous solution and saponification degree had some effect on the percentage extraction of metal ions. The distribution coefficient of the..... More

Separation of Rhenium (VII) and Vanadium (V) from Hydrochloric Acid Solutions by Solvent Extraction
Thi Hong Nguyen, Hoai Thanh Truong, Man Seung Lee
Korean J. Met. Mater. 2017;55(10):724-731.   Published online 2017 Sep 28
DOI: https://doi.org/10.3365/KJMM.2017.55.10.724

The separation of Re(VII) and V(V) by solvent extraction with TBP was investigated by varying the HCl, metal and chloride ion concentrations. Re(VII) was selectively extracted over V(V) from the HCl solution. The highest separation between Re(VII) and V(V) occurred at a concentration of 2.0 M HCl. The extraction reaction..... More

Solvent Extraction of Tungsten(VI) from Moderate Hydrochloric Acid Solutions with LIX 63
Hoai Thanh Truong, Yong Hwan Kim, Man Seung Lee
Korean J. Met. Mater. 2017;55(6):405-411.   Published online 2017 Jun 1
DOI: https://doi.org/10.3365/KJMM.2017.55.6.405

The solvent extraction of tungsten(VI) from hydrochloric acid solutions using 5,8-diethyl- 7-hydroxydodecan-6-one oxime (LIX 63) was analyzed in solutions having an initial pH range from 2 to 5, by varying the concentration of metal and extractant. In our experimental range, the cationic exchange reaction as well as the solvation reaction..... More

         Cited By 1
Separation and Recovery of Precious Metals from Leach Liquors of Spent Electronic Wastes by Solvent Extraction
Thi Hong Nguyen, Lingyun Wang, Man Seung Lee
Korean J. Met. Mater. 2017;55(4):247-255.   Published online 2017 Apr 6
DOI: https://doi.org/10.3365/KJMM.2017.55.4.247

Solvent extraction was employed to recover precious metals (Au (III), Pd (II) and Pt (IV)) from the leach solution of spent electronic wastes containing Cu (II), Cr (III) and Fe (III). First, pure Fe (III) and Au (III) were recovered by simultaneous extraction with Cyanex 923 followed by selective stripping..... More

         Cited By 4
Smelting & Refining
Separation of Rhenium(VII) and Vanadium(V) from concentrated HCl solution by solvent extraction with Alamine 336 and LIX 63
진한 염산용액에서 Alamine 336과 LIX 63의 용매추출에 의한 레늄(VII)과 바나듐(V)의 분리
Ji-Won Baek, Man-Seung Lee
백지원, 이만승
Korean J. Met. Mater. 2017;55(1):31-38.   Published online 2017 Jan 5
DOI: https://doi.org/10.3365/KJMM.2017.55.1.31

Solvent extraction experiments were performed with Re(VII) and V(V) from concentrated HCl solutions. In this work, Alamine 336 and LIX 63 were employed as the basic and cationic extractants. At an HCl concentration range from 1 to 5 M, Re(VII) was selectively extracted by Alamine 336, while V(V) was selectively..... More

         Cited By 1
Solvent Extraction of Pr and Nd from Chloride Solution by Mixtures of Acidic Extractants and LIX 63
Yang Liu, Ho Seok Jeon, Man Seung Lee
Korean J. Met. Mater. 2016;54(8):592-597.   Published online 2016 Aug 5
DOI: https://doi.org/10.3365/KJMM.2016.54.8.592

Mixtures of acidic extractants and LIX 63 were employed to improve the extraction efficiency of Pr and Nd from chloride solutions. The effect of the composition of the extractant mixtures has been studied. The order of metal extraction by single acidic extractant was D2EHPA > PC88A > Cyanex 272 >..... More

         Cited By 4
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